Chloride-catalyzed, multicomponent self-assembly of arsenic thiolates.
نویسندگان
چکیده
We present the observation that chloride serves as a simple catalyst for the acceleration of a self-assembly reaction between AsCl3 and dithiolate ligands (H2L) to form As2L3 assemblies. Studies on a model monomeric arsenic complex suggest that chloride may accelerate ligand exchange dynamics in pnictogen thiolates in general.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 1 شماره
صفحات -
تاریخ انتشار 2014